EU Safety Data Sheet – CIRRUS Fragrance Oil
1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND THE COMPANY
1.1 Product Identifier
| Product |
|---|
| CIRRUS E22039226 |
1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against
Perfume composition, flavor, aromatic ingredient, or blends of food additives and ingredients, for industrial use, which may be used in end-user products.
1.3 Details of the Supplier of the Safety Data Sheet
| Field | Details |
|---|---|
| Supplier | STOCK FRAGRANCE |
| Address | PO BOX 253, RIVER EDGE, NJ 07661 |
| Telephone | 347-989-4511 (Only during office hours) |
| hello@stockfragrance.com |
1.4 Emergency Telephone Number
| Region | Emergency telephone |
|---|---|
| North America | CHEMTREC 1-703-527-3887 / 1-800-424-9300 |
| Regional | NCEC +1 215 207 0061 |
| Europe | NCEC +44 1235 239670 |
| Middle East / Africa | NCEC +44 1235 239671 |
| Asia | NCEC +65 3158 1074 |
2 HAZARDS IDENTIFICATION
2.1 Classification of the Substance or Mixture
Classification according to Regulation (EC) No. 1272/2008 (CLP).
| Hazard Category | Classification |
|---|---|
| Physical hazards | No hazard specified. |
| Health hazards | No hazard specified. |
| Environmental | Aquatic Chronic 3: Harmful to aquatic life with long lasting effects. |
2.2 Label Elements
Signal word: No recommendation given.
Pictogram: No recommendation given.
Hazard Statements
| Code | Statement |
|---|---|
| H412 | Harmful to aquatic life with long lasting effects. |
Precautionary Statements
| Code | Statement |
|---|---|
| P273 | Avoid release to the environment. |
| P501 | Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
Supplemental Hazard Information
| Code | Statement |
|---|---|
| EUH208 | Contains 9-DECEN-2-ONE. May produce an allergic reaction. |
2.3 Other Hazards
| Property | Result |
|---|---|
| PBT substances, vPvB substances | None |
| Endocrine disruptors | None |
| Other information | None |
For a complete list of references and phrases mentioned in this chapter, see Section 16.
3 COMPOSITION / INFORMATION ON INGREDIENTS
3.1 Substances
CAS-No.: Not applicable
3.2 Mixtures — Hazardous Substances
| Component | CAS number | Concentration limit | Classification (Reg. 1272/2008/CE) |
|---|---|---|---|
| ME-(TRIMETHYLCYCLOPENTENYL)BUTENOL | 28219-60-5 | [10 % , 20 %[ | Aquatic Chronic 2, H411 |
| AMBROX | 3738-00-9 | [0.1 % , 1 %[ | Repr. 2, H361 |
| 9-DECEN-2-ONE | 35194-30-0 | [0.1 % , 1 %[ | Skin Sens. 1B, H317 STOT SE 3 (NE), H336 |
Concentration limits are stated as half-open intervals: [10 % , 20 %[ means at least 10 % and less than 20 %.
Registration and Other Hazard Information
| Component | REACH number | M factor | SCL |
|---|---|---|---|
| ME-(TRIMETHYLCYCLOPENTENYL)BUTENOL | 01-2120273309-51-XXXX | Not applicable | Not applicable |
| AMBROX | 01-2119976315-31-XXXX | Not applicable | Not applicable |
| 9-DECEN-2-ONE | 01-2120921116-65-0000 | Not applicable | Not applicable |
No Index number is assigned to any listed component.
The REACH number is specific to the manufacturer's legal entity.
Acute Toxicity Estimates (ATE) by Component
| Component | ATE LD50 Dermal | ATE LD50 Oral | ATE CL50 Inhalation – vapor |
|---|---|---|---|
| ME-(TRIMETHYLCYCLOPENTENYL)BUTENOL | > 5000 mg/kg | > 5000 mg/kg | > 100 mg/l |
| AMBROX | N/A mg/kg | N/A mg/kg | N/A mg/l |
| 9-DECEN-2-ONE | > 5000 mg/kg | 2500 mg/kg | > 100 mg/l |
Ingredients having an occupational exposure limit value: See Section 8.
4 FIRST AID MEASURES
4.1 Description of First Aid Measures
| Scenario | Measure |
|---|---|
| IF ON SKIN (or hair) | Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. |
| IF IN EYES | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| IF SWALLOWED | Rinse mouth. Do NOT induce vomiting. |
| IF INHALED | Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
4.2 Most Important Symptoms and Effects, Both Acute and Delayed
Get medical attention if symptoms persist.
4.3 Indication of Any Immediate Medical Attention and Special Treatment Needed
Never give liquid to an unconscious person.
5 FIRE-FIGHTING MEASURES
5.1 Extinguishing Media
Water, CO2 or Foam.
Extinguishing media to avoid: Avoid water in straight hose stream; will scatter and spread fire.
5.2 Special Hazards Arising from the Substance or Mixture
Avoid breathing dust or vapor. Cool containers exposed to flames with water until well after the fire is out.
5.3 Advice for Firefighters
No specific precautions.
6 ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions, Protective Equipment and Emergency Procedures
Contain spillages with sand, earth or any suitable adsorbent material.
6.2 Environmental Precautions
There must be no release into the environment.
6.3 Methods and Material for Containment and Clean-Up
Collect with non-combustible absorbent material. Flush with water. Dike for large spills.
6.4 Reference to Other Sections
See Section 8 of the SDS for Personal Protective Equipment. For waste disposal, see Section 13 of the SDS.
7 HANDLING AND STORAGE
7.1 Precautions for Safe Handling
Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate.
Store in a cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high temperatures.
Do not breathe vapor from heated material.
7.2 Condition for Safe Storage, Including Any Incompatibilities
Keep only in the original container in an appropriate place.
7.3 Specific End Use(s)
No specific precautions.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control Parameters
Occupational exposure limits — National OEL values:
| Country | OEL |
|---|---|
| France | None |
| Germany | None |
| United States of America | None |
| Argentina | None |
| Brazil | None |
| China | None |
| Indonesia | None |
| Japan | None |
| Poland | None |
European Indicative OEL values: None
8.2 Exposure Controls
Face & Eye Protection
Use safety glasses or a face shield according to Standard EN 166 and according to the hazard analysis specific to the workplace (chemical to be handled, protocol for use, frequency of use, quantity used, etc.).
Hand & Skin Protection
Use chemical resistant gloves in accordance with Standard EN 374 for protective gloves against chemicals. When prolonged or frequently repeated contact may occur, a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes according to Standard EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to Standard EN 374) is recommended. Thickness > or = 0.2 mm.
Please observe the instructions regarding permeability and breakthrough time which are provided by the glove supplier. Permeation time must exceed contact time. Choose the type of gloves according to the chemical properties of the products being handled. Change gloves according to the manufacturer's recommendations or if they are damaged.
Wear protective clothing covering the arms and legs. Use an apron or full suit if exposure is expected.
Respiratory Protection
Use in a well-ventilated area. In the event that ventilation is not sufficient to prevent inhalation of substances or reduce airborne concentrations below an established occupational exposure limit, use an adequate respiratory apparatus with filter type ABEK1 P3 (EN 14387) to supplement the engineering measures already in place.
These recommendations must be adapted according to the hazard analysis specific to the workplace.
9 PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on Basic Physical and Chemical Properties
| Property | Value |
|---|---|
| Physical State | LIQUID |
| Color | From COLORLESS to YELLOW |
| Odor | Characteristic |
| pH | No data available. |
| Melting point (°C) | No data available. |
| Boiling point (°C) | No data available. |
| Flash point (°C) | >100 °C |
| Evaporation Rate | No data available. |
| Flammability (solid, gas) | No data available. |
| Upper/lower limit on flammability or explosive limits | No data available. |
| Vapor pressure | 0.00 mmHg |
| Vapor Density | No data available. |
| Specific Gravity | 0.9287 / 0.9387 |
| Solubility | No data available. |
| Log Pow (n-Octanol/Water Partition Coefficient) | No data available. |
| Auto Ignition Temp. (°C) | No data available. |
| Decomposition temperature (°C) | No data available. |
| Viscosity at 40°C | No data available. |
| Explosive properties | No data available. |
| Oxidizing properties | No data available. |
| Vapor pressure at 20°C | No data available. |
| Vapor pressure at 50°C | No data available. |
9.2 Other Information
No other information noted.
10 STABILITY AND REACTIVITY
10.1 Reactivity
No data available.
10.2 Chemical Stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
No data available.
10.4 Conditions to Avoid
Store in a cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high temperatures.
10.5 Incompatible Materials
No data available.
10.6 Hazardous Decomposition Products
No data available.
11 TOXICOLOGICAL INFORMATION
11.1 Hazard Class Information as Defined in Regulation (EC) No. 1272/2008
Product information:
| Endpoint | Value |
|---|---|
| LD50 Dermal (mg/kg) | > 5000 (Unknown: 0%) (Calculated) |
| LD50 Oral (mg/kg) | > 5000 (Unknown: 0%) (Calculated) |
| LC50 Inhalation – vapor (mg/l) | > 100 (Unknown: 0%) (Calculated) |
Component information:
| Component | CAS | Concentration limit | LD50 Dermal (mg/kg) | LD50 Oral (mg/kg) | CL50 Inhalation – vapor (mg/l) |
|---|---|---|---|---|---|
| AMBROX | 3738-00-9 | [0.1 % , 1 %[ | No data available. | No data available. | No data available. |
| 9-DECEN-2-ONE | 35194-30-0 | [0.1 % , 1 %[ | > 5000 (Estimated) | 2500 (Estimated) | > 100 (Estimated) |
| Endpoint | Result |
|---|---|
| Serious eye damage/irritation | No data available. |
| Germ cell mutagenicity | No data available. |
| Reproductive toxicity | No data available. |
| Specific Target Organ – Single Exposure | No data available. |
| Skin Sensitization | No data available. |
| Carcinogenicity | No data available. |
| Specific Target Organ (NE) – Single Exposure | No data available. |
| Specific Target Organ – Repeated Exposure | No data available. |
| Aspiration Hazard | No data available. |
| Respiratory Sensitization | No data available. |
| Skin corrosion/irritation | No data available. |
| Information on likely routes of exposure | No data available. |
| Symptoms related to the physical, chemical, and toxicological characteristics | No data available. |
| Delayed, immediate, and chronic effects of short- and long-term exposure | No data available. |
| Interactive effects | No data available. |
11.2 Endocrine Disrupting Properties
Properties interfering with the endocrine system: Not applicable
Other information: No data available.
12 ECOLOGICAL INFORMATION
12.1 Toxicity
| Endpoint | Value |
|---|---|
| Toxicity Fish | No data available. |
| Toxicity Alga | No data available. |
| Toxicity Water Flea | No data available. |
12.2 Persistence and Degradability
| Property | Value |
|---|---|
| Biodegradability | No data available. |
| Hydrosolubility | No data available. |
| Comments | None |
12.3 Bioaccumulative Potential
| Property | Value |
|---|---|
| Log Pow (n-Octanol/Water Partition Coefficient) | No data available. |
| Bio Concentration Factor | No data available. |
12.4 Mobility in Soil
No data available.
12.5 Results of PBT and vPvB Assessment
No data available.
12.6 Endocrine Disrupting Properties
Properties interfering with the endocrine system: Not applicable
Other information: No data available.
12.7 Other Adverse Effects
No data available.
13 DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Do not release into the environment. Confirm disposal procedures with environmental engineer and local regulations.
13.2 Other Information
Always keep original label(s) on empty recipients (drums/pails).
14 TRANSPORT INFORMATION
| Mode | Status |
|---|---|
| ADR (Road) | Not regulated |
| RID (Rail) | Not regulated |
| IMDG (Sea) | Not regulated |
| IATA (Air) | Not regulated |
14.1 Special Precautions for User
No recommendation given.
15 REGULATORY INFORMATION
15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture
| Regulation | Detail |
|---|---|
| Water Hazard Class (WGK) | WGK 2 (Hazard to waters) |
| SEVESO III | Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. |
| ICPE nomenclature (France) | Not applicable |
Other regulations can apply: Directive 92/85/EEC on maternity protection, or stricter national regulations if applicable. Directive 94/33/EC on the protection of young people at work, or stricter national regulations if applicable.
15.2 Chemical Safety Assessment
No data available.
16 OTHER INFORMATION
16.1 Entire Text of the H and P Phrases Mentioned in Sections 2 and 3
| Code | Statement |
|---|---|
| H317 | May cause an allergic skin reaction. |
| H336 | May cause drowsiness or dizziness. |
| H361 | Suspected of damaging fertility or the unborn child. |
| H411 | Toxic to aquatic life with long lasting effects. |
| H412 | Harmful to aquatic life with long lasting effects. |
| EUH208 | Contains 9-DECEN-2-ONE. May produce an allergic reaction. |
| P273 | Avoid release to the environment. |
| P501 | Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
16.2 Abbreviations and Acronyms
| Abbreviation | Meaning |
|---|---|
| CAS | Chemical Abstracts Service |
| CO2 | Carbon dioxide |
| LD50 | Lethal dose 50 |
| NTP | National Toxicology Program |
| IARC | International Agency for Research on Cancer |
| OSHA | Occupational Safety and Health Administration |
| UN | United Nations |
| IMDG | International Maritime Dangerous Goods |
| IATA | International Air Transport Association |
| ADR | European Agreement concerning the International Carriage of Dangerous Goods by Road |
| RID | Regulations concerning the International Carriage of Dangerous Goods by Rail |
| ATE | Acute Toxicity Estimate |
| SCL | Specific Concentration Limit |
| M factor | Multiplying factor for substances very toxic to the aquatic environment |
| REACH | Registration, Evaluation, Authorisation and Restriction of Chemicals |
| PBT / vPvB | Persistent, Bioaccumulative and Toxic / very Persistent and very Bioaccumulative |
| WGK | Wassergefährdungsklasse (German Water Hazard Class) |
Classification Codes
| Code | Meaning |
|---|---|
| Aquatic Chronic 2 | Chronic hazards to the aquatic environment, Category 2 |
| Aquatic Chronic 3 | Chronic hazards to the aquatic environment, Category 3 |
| Repr. 2 | Toxic for reproduction, Category 2 |
| Skin Sens. 1B | Skin sensitizer, Category 1B |
| STOT SE 3 (NE) | Specific target organ toxicity – single exposure, Category 3, narcotic effect |
16.3 Key Literature References and Sources for Data
This Safety Data Sheet has been prepared in accordance with Regulation (EC) No. 1907/2006 and its amendments. The information given corresponds to the knowledge we have on the date mentioned on this document and is based on the recommendations of the EFFA and IOFI/IFRA working groups.
We cannot be held responsible in the event of improper usage of this product. It is up to the user to analyse the information given and to determine appropriate handling conditions for the safe use of this product. It is the user's liability to conform to all local, national, and international regulations that apply to its activities.
This automatically generated safety data sheet is valid without signature.
Learn more: U.S. vs EU Fragrance Labeling · Solvents in Fragrance Oils · How to Store Fragrance Oils
Frequently Asked Questions
What is an EU Safety Data Sheet, and how is it different from the US SDS?
An EU Safety Data Sheet is prepared to the format of Annex II of Regulation (EC) No 1907/2006 (REACH), with hazards classified under Regulation (EC) No 1272/2008 (CLP). It is published alongside the US GHS Safety Data Sheet for Cirrus, not in place of it: the two sheets classify the same fragrance oil under two different legal systems and carry different label elements, so a product sold in the EU is labelled from this sheet and a product sold in the US from the US sheet.
What extra information does the EU SDS give for Cirrus fragrance oil?
Section 3 lists every hazardous component with its CAS number, REACH registration number, EU index number where one is assigned, concentration range, CLP classification, M-factor, specific concentration limit and acute toxicity estimates. Section 2 carries any EUH208 sensitiser statement, and Sections 2.3, 11.2 and 12.6 address PBT, vPvB and endocrine-disrupting properties. None of these appear on the US sheet.
Does Cirrus fragrance oil require special handling or PPE?
Handle in a well-ventilated area with chemical-resistant gloves to EN 374 and eye protection to EN 166, and avoid prolonged skin contact. Section 8 of this sheet gives the full personal protective equipment guidance, and Section 7 the storage conditions.
What should I do if Cirrus fragrance oil contacts skin or eyes?
For skin contact, remove contaminated clothing and rinse the skin with water. For eye contact, rinse cautiously with water for several minutes, removing contact lenses if present and easy to do, and continue rinsing. Get medical attention if symptoms persist. Section 4 of this sheet gives the full first-aid measures and Section 1.4 the emergency telephone numbers.