Adirondack Fragrance Oil Safety Data Sheet

STOCK FRAGRANCE
Safety Data Sheet
ADIRONDACK E22206708
ADIRONDACK E22206708
Issue date: 12 JAN 2023  ·  Version 1
1   Product and Company Identification
1.1   Product Identifier
ADIRONDACK E22206708
1.2   Relevant Identified Uses
Perfume composition, flavour or aromatical ingredient, for an industrial usage, that can be used in end-user product.
1.3   Details of the Supplier
Supplier: STOCK FRAGRANCE
Address: PO BOX 253, RIVER EDGE, NJ 07661
Telephone: 347-989-4511
Email: hello@stockfragrance.com
1.4   Emergency Telephone Number
NCEC (regional): +1 215 207 0061
2.1   Classification of the Substance or Mixture
Physical hazards: Flam. Liq. 4 — Combustible liquid.
Health dangers: Skin Sens. 1 — May cause an allergic skin reaction. Eye Irrit. 2A — Causes serious eye irritation.
Environmental hazards: Aquatic Chronic 2 — Toxic to aquatic life with long lasting effects.
2.2   Label Elements
GHS Pictograms:
GHS07 Exclamation Mark – irritant, narcotic effects, respiratory tract irritationGHS07
GHS09 Environment – aquatic toxicityGHS09
Signal Word: WARNING
Hazard Statements:
Code Statement
H227 Combustible liquid.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements:
Code Statement
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P273 Avoid release to the environment.
P333+P313 If skin irritation or rash occurs: Get medical advice.
P370+P378 In case of fire: Use water for extinction.
P305+P351+P338 IF IN EYES: Rinse with water for several minutes. Remove contact lenses, if present.
P337+P313 If eye irritation persists: Get medical advice.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P391 Collect spillage.
P321 Specific treatment (see this label).
P363 Wash contaminated clothing before reuse.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
P272 Contaminated work clothing should not be allowed out of the workplace.
2.3   Other Hazards
None
3   Composition / Information on Ingredients
3.1   Substances
CAS-No.: Not applicable
3.2   Mixtures — Hazardous Substances
Component CAS Concentration Classification
BENZYL BENZOATE 120-51-4 ≥ 10% – 20% Acute Tox. 4 Oral, H302; Aquatic Acute 1, H400; Aquatic Chronic 2, H411
p-tert-BUTYL CYCLOHEXYL ACETATE 32210-23-4 ≥ 10% – 20% Skin Sens. 1B, H317
BENZYL ALCOHOL 100-51-6 ≥ 5% – 10% Acute Tox. 4 Oral, H302; Eye Irrit. 2A, H319
OCTAHYDRO TETRAMETHYL ACETONAPHTONE 54464-57-2 ≥ 5% – 10% Skin irrit. 2, H315; Skin Sens. 1B, H317; Aquatic Chronic 1, H410
VANILLIN 121-33-5 ≥ 1% – 5% Eye Irrit. 2A, H319
ETHYL VANILLIN 121-32-4 ≥ 1% – 5% Eye Irrit. 2B, H320
Distillates (petroleum), hydrotreated light 64742-47-8 ≥ 1% – 5% Flam. Liq. 4, H227; Asp. Tox. 1, H304; STOT SE 3 (NE), H336; Aquatic Chronic 2, H411
ETHYL MALTOL 4940-11-8 ≥ 1% – 5% Acute Tox. 4 Oral, H302
EUGENOL 97-53-0 ≥ 1% – 5% Skin Sens. 1B, H317; Eye Irrit. 2A, H319
CAMPHENE 79-92-5 ≥ 0.1% – 1% Flam. Sol. 2, H228; Eye Irrit. 2B, H320; Aquatic Acute 1, H400; Aquatic Chronic 1, H410
alpha CEDRENE 469-61-4 ≥ 0.1% – 1% Asp. Tox. 1, H304; Skin irrit. 2, H315; Aquatic Acute 1, H400; Aquatic Chronic 1, H410
LORENOX 900779-74-0 ≥ 0.1% – 1% Skin Sens. 1B, H317; Eye Irrit. 2A, H319; Aquatic Acute 1, H400; Aquatic Chronic 1, H410
Alpha PINENE 80-56-8 ≥ 0.1% – 1% Flam. Liq. 3, H226; Acute Tox. 4 Oral, H302; Asp. Tox. 1, H304; Skin irrit. 2, H315; Skin Sens. 1B, H317; Aquatic Acute 1, H400; Aquatic Chronic 1, H410
DELTA 3 CARENE 13466-78-9 ≥ 0.1% – 1% Flam. Liq. 3, H226; Asp. Tox. 1, H304; Skin irrit. 2, H315; Skin Sens. 1, H317; Acute Tox. 4 Inhalation, H332; Aquatic Chronic 2, H411
METHYLCYCLOPENTENOLONE 80-71-7 ≥ 0.1% – 1% Acute Tox. 4 Oral, H302; Skin Sens. 1, H317
LIMONENES 138-86-3 ≥ 0.1% – 1% Flam. Liq. 3, H226; Asp. Tox. 1, H304; Skin irrit. 2, H315; Skin Sens. 1B, H317; Aquatic Acute 1, H400; Aquatic Chronic 3, H412
Ingredients having an occupational exposure limit value: See Section 8.
4   First Aid Measures
4.1   Description of First Aid Measures
IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
4.2   Most Important Symptoms and Effects
Get medical attention if symptoms persist.
4.3   Immediate Medical Attention
Never give liquid to an unconscious person.
5   Fire-Fighting Measures
5.1   Suitable Extinguishing Media
Water, CO₂ or Foam. Avoid water in straight hose stream; will scatter and spread fire.
5.2   Special Hazards
Avoid breathing dust or vapor. Cool containers exposed to flames with water until well after the fire is out.
5.3   Advice for Firefighters
No specific precautions.
6   Accidental Release Measures
6.1   Personal Precautions
Contain spillages with sand, earth or any suitable adsorbent material.
6.2   Environmental Precautions
There must be no release into the environment.
6.3   Containment and Cleanup
Collect with non-combustible absorbent material. Flush with water. Dike for large spills.
6.4   Reference to Other Sections
See Section 8 for Personal Protective Equipment. See Section 13 for waste disposal.
7   Handling and Storage
7.1   Precautions for Safe Handling
Keep strict control of dust accumulation to a minimum. Maintain adequate local and general ventilation where product is handled. Avoid any sources of ignition. Good personal washing routines should be followed.
7.2   Conditions for Safe Storage
Keep only in the original container in an appropriate place.
7.3   Specific End Uses
No specific precautions.
8   Exposure Controls / Personal Protection
8.1   Control Parameters
Component CAS Concentration OEL (ppm)
BENZYL ALCOHOL 100-51-6 ≥ 5% – 10% 10 (AIHA)
8.2   Exposure Controls
Environmental: Discharge, treatment, or disposal may be subject to national, state, or local laws.
Respiratory: In case of inadequate ventilation use suitable respirator.
Eye: Wear goggles/face shield.
Hand: Gloves.
Skin: Wear suitable protective clothing. Provide adequate ventilation if fumes or vapors are generated.
9   Physical and Chemical Properties
9.1   Basic Physical and Chemical Properties
Property Value
Physical State Liquid
Color Colorless to Yellow
Odor Characteristic
pH No data available
Melting Point No data available
Boiling Point No data available
Flash Point 194.82 °F (90.4 °C)
Evaporation Rate No data available
Flammability (solid, gas) No data available
Upper/Lower Flammability Limits No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 0.9814 / 0.9914
Solubility No data available
Log Pow No data available
Auto Ignition Temp. No data available
Decomposition Temp. No data available
Viscosity at 40 °C No data available
Explosive Properties No data available
Oxidizing Properties No data available
9.2   Other Information
No other information noted.
10   Stability and Reactivity
10.1   Reactivity
No data available.
10.2   Chemical Stability
Stable under normal temperature conditions and recommended use.
10.3   Possibility of Hazardous Reactions
No data available.
10.4   Conditions to Avoid
Store in a cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high temperatures.
10.5   Incompatible Materials
No data available.
10.6   Hazardous Decomposition Products
No data available.
11   Toxicological Information
11.1   Toxicological Effects
Endpoint Value
LD50 Dermal (mg/kg) > 5000 (Calculated)
LD50 Oral (mg/kg) 3917.2 (Calculated)
LC50 Inhalation — vapor (mg/L) > 100 (Calculated)
11.2   Other Toxicological Data
This product has not been subject to toxicological testing as an entity. According to available data on the constituents, the health classification criteria are met.
11.3   Carcinogen Information
NTP: None  ·  IARC: None  ·  OSHA: None
12   Ecological Information
12.1   Toxicity
Toxicity Fish: No data available. Toxicity Alga: No data available. Toxicity Water Flea: No data available. Toxicity Rat: No data available.
12.2   Persistence and Degradability
Biodegradability: No data available. Hydrosolubility: No data available.
12.3   Other Eco-Toxicological Information
This product has not been subject to eco-toxicological testing as an entity. According to available data on the constituents, the environment classification criteria are met.
Log Pow: No data available. Bio Concentration Factor: No data available. Bioaccumulative potential: No data available. Mobility in soil: No data available. Other adverse effects: No data available.
13   Disposal Considerations
13.1   Waste Treatment Methods
Do not release into the environment. Confirm disposal procedures with environmental engineer and local regulations.
13.2   Other Information
Always keep original label(s) on empty recipients (drums/pails).
14   Transport Information
DOT (US Department of Transportation)
Field Value
UN Number 3082
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS)
Danger Class Class 9: Miscellaneous Dangerous Substances and Articles
Packaging Group III
Environmental Dangers Yes
IATA (International Air Transport)
Field Value
UN Number 3082
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS)
Danger Class Class 9: Miscellaneous Dangerous Substances and Articles
Packaging Group III
Environmental Dangers Yes
IMDG (International Maritime)
Field Value
UN Number 3082
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS)
Danger Class Class 9: Miscellaneous Dangerous Substances and Articles
Packaging Group III
Environmental Dangers Yes
Marine Pollutants P — pollutant
15   Regulatory Information
Safety, health and environmental regulations/legislation specific for the substance or mixture: No recommendation given. Prepared in accordance with the OSHA Hazard Communication Standard (HCS) — 29 CFR 1910.1200.
16   Other Information
16.1   Full Text of H and P Phrases
Code Full Text
H226 Flammable liquid and vapor.
H227 Combustible liquid.
H228 Flammable solid.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H320 Causes eye irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
16.2   Abbreviations and Acronyms
CAS: Chemical Abstracts Service  ·  CO₂: Carbon dioxide  ·  LD50: Lethal dose 50  ·  NTP: National Toxicology Program  ·  IARC: International Agency for Research on Cancer  ·  OSHA: Occupational Safety and Health Administration  ·  UN: United Nations  ·  IMDG: International Maritime Dangerous Goods  ·  IATA: International Air Transport Association
This automatically generated Safety Data Sheet is valid without signature. The information provided is correct to the best of our knowledge, information and belief at the date of its publication. The information is provided as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.