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Vanillamour Fragrance Oil EU Safety Data Sheet

STOCK FRAGRANCE
EU Safety Data Sheet
VANILLAMOUR E23044944

EU Safety Data Sheet – VANILLAMOUR Fragrance Oil

E23044944

1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND THE COMPANY

1.1 Product Identifier

Product
VANILLAMOUR E23044944

1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against

Perfume composition, flavor, aromatic ingredient, or blends of food additives and ingredients, for industrial use, which may be used in end-user products.

1.3 Details of the Supplier of the Safety Data Sheet

Field Details
Supplier STOCK FRAGRANCE
Address PO BOX 253, RIVER EDGE, NJ 07661
Telephone 347-989-4511 (Only during office hours)
e-mail hello@stockfragrance.com

1.4 Emergency Telephone Number

Region Emergency telephone
Regional NCEC +1 215 207 0061
Europe NCEC +44 1235 239670
Middle East / Africa NCEC +44 1235 239671
Asia NCEC +65 3158 1074

2 HAZARDS IDENTIFICATION

2.1 Classification of the Substance or Mixture

Classification according to Regulation (EC) No. 1272/2008 (CLP).
Hazard Category Classification
Physical hazards No hazard specified.
Health hazards Skin Sens. 1: May cause an allergic skin reaction.
Environmental Aquatic Acute 1: Very toxic to aquatic life.
Environmental Aquatic Chronic 2: Toxic to aquatic life with long lasting effects.

2.2 Label Elements

Signal word: WARNING
Pictogram:
GHS07GHS07
GHS09GHS09

Hazard Statements

Code Statement
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

Code Statement
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P273 Avoid release to the environment.
P333+P313 If skin irritation or rash occurs: Get medical advice.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P391 Collect spillage.
P321 Specific treatment (see this label).
P363 Wash contaminated clothing before reuse.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
P272 Contaminated work clothing should not be allowed out of the workplace.

Supplemental Hazard Information

Code Statement
EUH208 Contains LORENOX, EUGENOL. May produce an allergic reaction.

2.3 Other Hazards

Property Result
PBT substances, vPvB substances None
Endocrine disruptors None
Other information None
For a complete list of references and phrases mentioned in this chapter, see Section 16.

3 COMPOSITION / INFORMATION ON INGREDIENTS

3.1 Substances

CAS-No.: Not applicable

3.2 Mixtures — Hazardous Substances

Component CAS number Concentration limit Classification (Reg. 1272/2008/CE)
BENZYL BENZOATE 120-51-4 [20 % , 50 %[ Acute Tox. 4 Oral, H302
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
p-tert-BUTYL CYCLOHEXYL ACETATE 32210-23-4 [10 % , 20 %[ Skin Sens. 1B, H317
HEXYL CINNAMAL 101-86-0 [5 % , 10 %[ Skin Sens. 1B, H317
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
ETHYL MALTOL 4940-11-8 [1 % , 5 %[ Acute Tox. 4 Oral, H302
VANILLIN 121-33-5 [1 % , 5 %[ Eye Irrit. 2, H319
METHYL 3,6-DIMETHYL RESORCYLATE 4707-47-5 [1 % , 5 %[ Skin Sens. 1B, H317
ETHER CEDRYL METHYL 2182025-97-2 [1 % , 5 %[ Skin Sens. 1B, H317
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
LINALOOL 78-70-6 [1 % , 5 %[ Skin irrit. 2, H315
Skin Sens. 1B, H317
Eye Irrit. 2, H319
ME-(TRIMETHYLCYCLOPENTENYL)BUTENOL 28219-60-5 [1 % , 5 %[ Aquatic Chronic 2, H411
2,6-dimethyloct-7-en-2-ol 18479-58-8 [1 % , 5 %[ Skin irrit. 2, H315
Eye Irrit. 2, H319
STOT SE 3 (NE), H336
LORENOX 900779-74-0 [0.1 % , 1 %[ Skin Sens. 1B, H317
Eye Irrit. 2, H319
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
EUGENOL 97-53-0 [0.1 % , 1 %[ Skin Sens. 1B, H317
Eye Irrit. 2, H319
Concentration limits are stated as half-open intervals: [10 % , 20 %[ means at least 10 % and less than 20 %.

Registration and Other Hazard Information

Component REACH number Index number M factor SCL
BENZYL BENZOATE 01-2119976371-33-XXXX 607-085-00-9 1 Not applicable
p-tert-BUTYL CYCLOHEXYL ACETATE 01-2119976286-24-XXXX Not assigned Not applicable Not applicable
HEXYL CINNAMAL 01-2119533092-50-XXXX Not assigned 1 Not applicable
ETHYL MALTOL 01-2120758795-36-XXXX Not assigned Not applicable Not applicable
VANILLIN 01-2119516040-60-XXXX Not assigned Not applicable Not applicable
METHYL 3,6-DIMETHYL RESORCYLATE 01-2120762759-36-XXXX Not assigned Not applicable Not applicable
ETHER CEDRYL METHYL 01-2120228335-61-XXXX Not assigned 1 Not applicable
LINALOOL 01-2119474016-42-0008 603-235-00-2 Not applicable Not applicable
ME-(TRIMETHYLCYCLOPENTENYL)BUTENOL 01-2120273309-51-XXXX Not assigned Not applicable Not applicable
2,6-dimethyloct-7-en-2-ol 01-2119457274-37-XXXX Not assigned Not applicable Not applicable
LORENOX 01-2120908121-71-0000 Not assigned 1 Not applicable
EUGENOL 01-2119971802-33-0005 Not assigned Not applicable Not applicable
The REACH number is specific to the manufacturer's legal entity.

Acute Toxicity Estimates (ATE) by Component

Component ATE LD50 Dermal ATE LD50 Oral ATE CL50 Inhalation – vapor
BENZYL BENZOATE > 5000 mg/kg 1160 mg/kg > 100 mg/l
p-tert-BUTYL CYCLOHEXYL ACETATE > 5000 mg/kg 3370 mg/kg > 100 mg/l
HEXYL CINNAMAL > 5000 mg/kg 3100 mg/kg > 100 mg/l
ETHYL MALTOL > 5000 mg/kg 1200 mg/kg > 100 mg/l
VANILLIN 2600 mg/kg 3300 mg/kg > 100 mg/l
METHYL 3,6-DIMETHYL RESORCYLATE > 5000 mg/kg > 5000 mg/kg > 100 mg/l
ETHER CEDRYL METHYL > 5000 mg/kg > 5000 mg/kg > 100 mg/l
LINALOOL > 5000 mg/kg 2790 mg/kg > 100 mg/l
ME-(TRIMETHYLCYCLOPENTENYL)BUTENOL > 5000 mg/kg > 5000 mg/kg > 100 mg/l
2,6-dimethyloct-7-en-2-ol > 5000 mg/kg 3020 mg/kg > 100 mg/l
LORENOX > 5000 mg/kg > 5000 mg/kg > 100 mg/l
EUGENOL > 5000 mg/kg 2300 mg/kg > 100 mg/l
Ingredients having an occupational exposure limit value: See Section 8.

4 FIRST AID MEASURES

4.1 Description of First Aid Measures

Scenario Measure
IF ON SKIN (or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED Rinse mouth. Do NOT induce vomiting.
IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing.

4.2 Most Important Symptoms and Effects, Both Acute and Delayed

Get medical attention if symptoms persist.

4.3 Indication of Any Immediate Medical Attention and Special Treatment Needed

Never give liquid to an unconscious person.

5 FIRE-FIGHTING MEASURES

5.1 Extinguishing Media

Water, CO2 or Foam.
Extinguishing media to avoid: Avoid water in straight hose stream; will scatter and spread fire.

5.2 Special Hazards Arising from the Substance or Mixture

Avoid breathing dust or vapor. Cool containers exposed to flames with water until well after the fire is out.

5.3 Advice for Firefighters

No specific precautions.

6 ACCIDENTAL RELEASE MEASURES

6.1 Personal Precautions, Protective Equipment and Emergency Procedures

Contain spillages with sand, earth or any suitable adsorbent material.

6.2 Environmental Precautions

There must be no release into the environment.

6.3 Methods and Material for Containment and Clean-Up

Collect with non-combustible absorbent material. Flush with water. Dike for large spills.

6.4 Reference to Other Sections

See Section 8 of the SDS for Personal Protective Equipment. For waste disposal, see Section 13 of the SDS.

7 HANDLING AND STORAGE

7.1 Precautions for Safe Handling

Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate.
Store in a cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high temperatures.
Do not breathe vapor from heated material.

7.2 Condition for Safe Storage, Including Any Incompatibilities

Keep only in the original container in an appropriate place.

7.3 Specific End Use(s)

No specific precautions.

8 EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control Parameters

Occupational exposure limits — National OEL values:
Country OEL
France None
Germany None
United States of America None
Argentina None
Brazil None
China None
Indonesia None
Japan None
Poland None
European Indicative OEL values: None

8.2 Exposure Controls

Face & Eye Protection

Use safety glasses or a face shield according to Standard EN 166 and according to the hazard analysis specific to the workplace (chemical to be handled, protocol for use, frequency of use, quantity used, etc.).

Hand & Skin Protection

Use chemical resistant gloves in accordance with Standard EN 374 for protective gloves against chemicals. When prolonged or frequently repeated contact may occur, a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes according to Standard EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to Standard EN 374) is recommended. Thickness > or = 0.2 mm.
Please observe the instructions regarding permeability and breakthrough time which are provided by the glove supplier. Permeation time must exceed contact time. Choose the type of gloves according to the chemical properties of the products being handled. Change gloves according to the manufacturer's recommendations or if they are damaged.
Wear protective clothing covering the arms and legs. Use an apron or full suit if exposure is expected.
These recommendations must be adapted according to the hazard analysis specific to the workplace.

Respiratory Protection

Use in a well-ventilated area. In the event that ventilation is not sufficient to prevent inhalation of substances or reduce airborne concentrations below an established occupational exposure limit, use an adequate respiratory apparatus to supplement the engineering measures already in place.
These recommendations must be adapted according to the hazard analysis specific to the workplace.

9 PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on Basic Physical and Chemical Properties

Property Value
Physical State LIQUID
Color From COLORLESS to YELLOW
Odor Characteristic
pH No data available.
Melting point (°C) No data available.
Boiling point (°C) No data available.
Flash point (°C) >100 °C
Evaporation Rate No data available.
Flammability (solid, gas) No data available.
Upper/lower limit on flammability or explosive limits No data available.
Vapor pressure 0.01 mmHg
Vapor Density No data available.
Specific Gravity 1.0086 / 1.0186
Solubility No data available.
Log Pow (n-Octanol/Water Partition Coefficient) No data available.
Auto Ignition Temp. (°C) No data available.
Decomposition temperature (°C) No data available.
Viscosity at 40°C No data available.
Explosive properties No data available.
Oxidizing properties No data available.
Vapor pressure at 20°C No data available.
Vapor pressure at 50°C No data available.

9.2 Other Information

No other information noted.

10 STABILITY AND REACTIVITY

10.1 Reactivity

No data available.

10.2 Chemical Stability

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

No data available.

10.4 Conditions to Avoid

Store in a cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high temperatures.

10.5 Incompatible Materials

No data available.

10.6 Hazardous Decomposition Products

No data available.

11 TOXICOLOGICAL INFORMATION

11.1 Hazard Class Information as Defined in Regulation (EC) No. 1272/2008

Product information:
Endpoint Value
LD50 Dermal (mg/kg) > 5000 (Unknown: 0%) (Calculated)
LD50 Oral (mg/kg) 2462.6 (Unknown: 0%) (Calculated)
LC50 Inhalation – vapor (mg/l) > 100 (Unknown: 0%) (Calculated)
Component information:
Component CAS Concentration limit LD50 Dermal (mg/kg) LD50 Oral (mg/kg) CL50 Inhalation – vapor (mg/l)
BENZYL BENZOATE 120-51-4 [20 % , 50 %[ > 5000 (Estimated) 1160 (Measured) > 100 (Estimated)
p-tert-BUTYL CYCLOHEXYL ACETATE 32210-23-4 [10 % , 20 %[ > 5000 (Estimated) 3370 (Estimated) > 100 (Estimated)
HEXYL CINNAMAL 101-86-0 [5 % , 10 %[ > 5000 (Estimated) 3100 (Estimated) > 100 (Estimated)
ETHYL MALTOL 4940-11-8 [1 % , 5 %[ > 5000 (Estimated) 1200 (Measured) > 100 (Estimated)
VANILLIN 121-33-5 [1 % , 5 %[ 2600 (Measured) 3300 (Measured) > 100 (Estimated)
METHYL 3,6-DIMETHYL RESORCYLATE 4707-47-5 [1 % , 5 %[ > 5000 (Estimated) > 5000 (Estimated) > 100 (Estimated)
ETHER CEDRYL METHYL 2182025-97-2 [1 % , 5 %[ > 5000 (Estimated) > 5000 (Estimated) > 100 (Estimated)
LINALOOL 78-70-6 [1 % , 5 %[ > 5000 (Measured) 2790 (Measured) > 100 (Estimated)
2,6-dimethyloct-7-en-2-ol 18479-58-8 [1 % , 5 %[ > 5000 (Estimated) 3020 (Estimated) > 100 (Estimated)
LORENOX 900779-74-0 [0.1 % , 1 %[ > 5000 (Estimated) > 5000 (Estimated) > 100 (Estimated)
EUGENOL 97-53-0 [0.1 % , 1 %[ > 5000 (Estimated) 2300 (Estimated) > 100 (Estimated)
Endpoint Result
Serious eye damage/irritation No data available.
Germ cell mutagenicity No data available.
Reproductive toxicity No data available.
Specific Target Organ – Single Exposure No data available.
Skin Sensitization No data available.
Carcinogenicity No data available.
Specific Target Organ (NE) – Single Exposure No data available.
Specific Target Organ – Repeated Exposure No data available.
Aspiration Hazard No data available.
Respiratory Sensitization No data available.
Skin corrosion/irritation No data available.
Information on likely routes of exposure No data available.
Symptoms related to the physical, chemical, and toxicological characteristics No data available.
Delayed, immediate, and chronic effects of short- and long-term exposure No data available.
Interactive effects No data available.

11.2 Endocrine Disrupting Properties

Properties interfering with the endocrine system: Not applicable
Other information: No data available.

12 ECOLOGICAL INFORMATION

12.1 Toxicity

Endpoint Value
Toxicity Fish No data available.
Toxicity Alga No data available.
Toxicity Water Flea No data available.

12.2 Persistence and Degradability

Property Value
Biodegradability No data available.
Hydrosolubility No data available.
Comments None

12.3 Bioaccumulative Potential

Property Value
Log Pow (n-Octanol/Water Partition Coefficient) No data available.
Bio Concentration Factor No data available.

12.4 Mobility in Soil

No data available.

12.5 Results of PBT and vPvB Assessment

No data available.

12.6 Endocrine Disrupting Properties

Properties interfering with the endocrine system: Not applicable
Other information: No data available.

12.7 Other Adverse Effects

No data available.

13 DISPOSAL CONSIDERATIONS

13.1 Waste Treatment Methods

Do not release into the environment. Confirm disposal procedures with environmental engineer and local regulations.

13.2 Other Information

Always keep original label(s) on empty recipients (drums/pails).

14 TRANSPORT INFORMATION

ADR (Road)

Field Details
UN number 3082
Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS)
Transport hazard class(es) Class 9: Miscellaneous dangerous substances and articles
Packing group III
Environmental hazards Yes
Tunnel restriction code

IATA (Air)

Field Details
UN number 3082
Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS)
Transport hazard class(es) Class 9: Miscellaneous dangerous substances and articles
Packing group III
Environmental hazards Yes

IMDG (Sea)

Field Details
UN number 3082
Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS) POLLUTANT
Transport hazard class(es) Class 9: Miscellaneous dangerous substances and articles
Packing group III
Environmental hazards Yes
Marine pollutant P – pollutant

RID (Rail)

Field Details
UN number 3082
Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS)
Transport hazard class(es) Class 9: Miscellaneous dangerous substances and articles
Packing group III
Environmental hazards Yes
Tunnel restriction code

14.1 Special Precautions for User

No recommendation given.

15 REGULATORY INFORMATION

15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture

Regulation Detail
Water Hazard Class (WGK) WGK 2 (Hazard to waters)
SEVESO III Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances.
ICPE nomenclature (France) Sections 4510, 4511
Other regulations can apply: Directive 92/85/EEC on maternity protection, or stricter national regulations if applicable. Directive 94/33/EC on the protection of young people at work, or stricter national regulations if applicable.

15.2 Chemical Safety Assessment

No data available.

16 OTHER INFORMATION

16.1 Entire Text of the H and P Phrases Mentioned in Sections 2 and 3

Code Statement
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
EUH208 Contains LORENOX, EUGENOL. May produce an allergic reaction.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P273 Avoid release to the environment.
P333+P313 If skin irritation or rash occurs: Get medical advice.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P391 Collect spillage.
P321 Specific treatment (see this label).
P363 Wash contaminated clothing before reuse.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
P272 Contaminated work clothing should not be allowed out of the workplace.

16.2 Abbreviations and Acronyms

Abbreviation Meaning
CAS Chemical Abstracts Service
CO2 Carbon dioxide
LD50 Lethal dose 50
NTP National Toxicology Program
IARC International Agency for Research on Cancer
OSHA Occupational Safety and Health Administration
UN United Nations
IMDG International Maritime Dangerous Goods
IATA International Air Transport Association
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
ATE Acute Toxicity Estimate
SCL Specific Concentration Limit
M factor Multiplying factor for substances very toxic to the aquatic environment
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
PBT / vPvB Persistent, Bioaccumulative and Toxic / very Persistent and very Bioaccumulative
WGK Wassergefährdungsklasse (German Water Hazard Class)

Classification Codes

Code Meaning
Acute Tox. 4 Oral Acute toxicity, Category 4, oral
Aquatic Acute 1 Acute hazards to the aquatic environment, Category 1
Aquatic Chronic 1 Chronic hazards to the aquatic environment, Category 1
Aquatic Chronic 2 Chronic hazards to the aquatic environment, Category 2
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Skin irrit. 2 Skin corrosion/irritation, Category 2
Skin Sens. 1 Skin sensitizer, Category 1
Skin Sens. 1B Skin sensitizer, Category 1B
STOT SE 3 (NE) Specific target organ toxicity – single exposure, Category 3, narcotic effect

16.3 Key Literature References and Sources for Data

This Safety Data Sheet has been prepared in accordance with Regulation (EC) No. 1907/2006 and its amendments. The information given corresponds to the knowledge we have on the date mentioned on this document and is based on the recommendations of the EFFA and IOFI/IFRA working groups.
We cannot be held responsible in the event of improper usage of this product. It is up to the user to analyse the information given and to determine appropriate handling conditions for the safe use of this product. It is the user's liability to conform to all local, national, and international regulations that apply to its activities.
This automatically generated safety data sheet is valid without signature.
Frequently Asked Questions

What is an EU Safety Data Sheet, and how is it different from the US SDS?

An EU Safety Data Sheet is prepared to the format of Annex II of Regulation (EC) No 1907/2006 (REACH), with hazards classified under Regulation (EC) No 1272/2008 (CLP). It is published alongside the US GHS Safety Data Sheet for Vanillamour, not in place of it: the two sheets classify the same fragrance oil under two different legal systems and carry different label elements, so a product sold in the EU is labelled from this sheet and a product sold in the US from the US sheet.

What extra information does the EU SDS give for Vanillamour fragrance oil?

Section 3 lists every hazardous component with its CAS number, REACH registration number, EU index number where one is assigned, concentration range, CLP classification, M-factor, specific concentration limit and acute toxicity estimates. Section 2 carries any EUH208 sensitiser statement, and Sections 2.3, 11.2 and 12.6 address PBT, vPvB and endocrine-disrupting properties. None of these appear on the US sheet.

Does Vanillamour fragrance oil require special handling or PPE?

Handle in a well-ventilated area with chemical-resistant gloves to EN 374 and eye protection to EN 166, and avoid prolonged skin contact. Section 8 of this sheet gives the full personal protective equipment guidance, and Section 7 the storage conditions.

What should I do if Vanillamour fragrance oil contacts skin or eyes?

For skin contact, remove contaminated clothing and rinse the skin with water. For eye contact, rinse cautiously with water for several minutes, removing contact lenses if present and easy to do, and continue rinsing. Get medical attention if symptoms persist. Section 4 of this sheet gives the full first-aid measures and Section 1.4 the emergency telephone numbers.

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