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ADIRONDACK Fragrance Oil SDS

1    PRODUCT AND COMPANY IDENTIFICATION

1.1    Product identifier

ADIRONDACK E22206708

1.2   Relevant identified uses of the substance or mixture and uses advised against

    Perfume composition, flavour or aromatical ingredient, for an industrial usage, that can be used in end-user product. 

    1.3    Details of the supplier of the safety data sheet

    Supplier STOCK FRAGRANCE

    Address PO BOX 180 RIVER EDGE NJ 07661

    Telephone 347-989-4511

    e-mail HELLO@STOCKFRAGRANCE.COM

    1.4    Emergency telephone number

    Emergency telephone number              : NCEC (regional) +1 215 207 0061

    2    HAZARDS IDENTIFICATION

    2.1    Classification of the substance or mixture

    Physical hazards

    Flam. Liq. 4: Combustible liquid.

    Health Dangers

    Skin Sens. 1: May cause an allergic skin reaction. Eye Irrit. 2A: Causes serious eye irritation.

    Environmental hazards

    Aquatic Chronic 2: Toxic to aquatic life with long lasting effects.

    2.2    Label elements

    Pictogram


     

     

    GHS07               GHS09

     

    Signal Word

    WARNING

    Hazard Statements

    H227: Combustible liquid.

    H317: May cause an allergic skin reaction. H319: Causes serious eye irritation.

    H411: Toxic to aquatic life with long lasting effects.

    Precautionary Statements

    P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280: Wear protective gloves/protective clothing/eye protection/face protection. P261: Avoid breathing dust/fume/gas/mist/vapors/spray.

    P273: Avoid release to the environment.

    P333+P313: If skin irritation or rash occurs: Get medical advice. P370+P378: In case of fire: Use water for extinction.

    P305+P351+P338: IF IN EYES: Rinse with water for several minutes. Remove contact lenses, if present. P337+P313: If eye irritation persists: Get medical advice

    P302+P352: IF ON SKIN: Wash with plenty of soap and water. P391: Collect spillage.

    P321: Specific treatment (see this label).

    P363: Wash contaminated clothing before reuse. P403+P235: Store in a well-ventilated place. Keep cool.

    P501: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    P272: Contaminated work clothing should not be allowed out of the workplace.

    2.3    Other hazards

    None

    3    COMPOSITION / INFORMATION ON INGREDIENTS

    3.1    Substances 

    CAS-No.:Not applicable

    3.2    Mixtures

    Hazardous Substances

    Component

    CAS

    Concentration limit

    CLASSIFICATION

    BENZYL BENZOATE

    120-51-4

    >= 10 % - 20 %

    Acute Tox. 4 Oral, H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411

    p-tert-BUTYL CYCLOHEXYL ACETATE

    32210-23-4

    >= 10 % - 20 %

    Skin Sens. 1B, H317

    BENZYL ALCOHOL

    100-51-6

    >= 5 % - 10 %

    Acute Tox. 4 Oral, H302 Eye Irrit. 2A, H319

    OCTAHYDRO TETRAMETHYL ACETONAPHTONE

    54464-57-2

    >= 5 % - 10 %

    Skin irrit. 2, H315 Skin Sens. 1B, H317

    Aquatic Chronic 1, H410

    VANILLIN

    121-33-5

    >= 1 % - 5 %

    Eye Irrit. 2A, H319

    ETHYL VANILLIN

    121-32-4

    >= 1 % - 5 %

    Eye Irrit. 2B, H320

    Distillates (petroleum), hydrotreated light

    64742-47-8

    >= 1 % - 5 %

    Flam. Liq. 4, H227 Asp. Tox. 1, H304 STOT SE 3 (NE), H336

    Aquatic Chronic 2, H411

    ETHYL MALTOL

    4940-11-8

    >= 1 % - 5 %

    Acute Tox. 4 Oral, H302

    EUGENOL

    97-53-0

    >= 1 % - 5 %

    Skin Sens. 1B, H317 Eye Irrit. 2A, H319

    CAMPHENE

    79-92-5

    >= 0.1 % - 1 %

    Flam. Sol. 2, H228 Eye Irrit. 2B, H320 Aquatic Acute 1, H400

    Aquatic Chronic 1, H410

    alpha CEDRENE

    469-61-4

    >= 0.1 % - 1 %

    Asp. Tox. 1, H304

    Skin irrit. 2, H315 Aquatic Acute 1, H400 Aquatic Chronic 1, H410

    LORENOX

    900779-74-0

    >= 0.1 % - 1 %

    Skin Sens. 1B, H317 Eye Irrit. 2A, H319 Aquatic Acute 1, H400 Aquatic Chronic 1, H410

    Alpha PINENE

    80-56-8

    >= 0.1 % - 1 %

    Flam. Liq. 3, H226 Acute Tox. 4 Oral, H302 Asp. Tox. 1, H304

    Skin irrit. 2, H315 Skin Sens. 1B, H317

    Aquatic Acute 1, H400 Aquatic Chronic 1, H410

    DELTA 3 CARENE

    13466-78-9

    >= 0.1 % - 1 %

    Flam. Liq. 3, H226 Asp. Tox. 1, H304

    Skin irrit. 2, H315 Skin Sens. 1, H317

    Acute Tox. 4 Inhalation, H332 Aquatic Chronic 2, H411

    METHYLCYCLOPENTENOLONE

    80-71-7

    >= 0.1 % - 1 %

    Acute Tox. 4 Oral, H302 Skin Sens. 1, H317

    LIMONENES

    138-86-3

    >= 0.1 % - 1 %

    Flam. Liq. 3, H226 Asp. Tox. 1, H304

    Skin irrit. 2, H315

    Skin Sens. 1B, H317

    Aquatic Acute 1, H400 Aquatic Chronic 3, H412

     

     

     

    Ingredients having an occupational exposure limit value: See section 8.

    4    FIRST AID MEASURES 

    4.1    Description of first aid measures

    IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.

    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

    IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

    4.2    Most important symptoms and effects, both acute and delayed

    Get medical attention if symptoms persist. 

    4.3    Indication of any immediate medical attention and special treatment needed

    Never give liquid to an unconscious person.

    5    FIRE-FIGHTING MEASURES

    5.1    Suitable extinguishing media

    Water, CO2 or Foam Extinguishing media to avoid

    Avoid water in straight hose stream; will scatter and spread fire.

    5.2    Special hazards arising from the substance or mixture

    Avoid breathing dust or vapor.

    Cool containers exposed to flames with water until well after the fire is out.

    5.3    Advice for firefighters

    No specific precautions.

    6    ACCIDENTAL RELEASE MEASURES

    6.1    Personal precautions, protective equipment and emergency procedures

    Contain spillages with sand, earth or any suitable adsorbent material.

    6.2    Environmental precautions

    There must be no release into the environment.

    6.3    Methods and materials for containment and cleanup procedure

    Collect with non-combustible absorbent material. Flush with water. Dike for large spills.

    6.4    Reference to other sections

    See Section 8 of the SDS for Personal Protective Equipment. For waste disposal, see section 13 of the SDS.

    7    HANDLING AND STORAGE

    7.1    Precautions for safe handling

    7.1.1  Protective measures

    Keep strict control of dust accumulation to a minimum.

    Maintain adequate local and general ventilation where product is handled. Avoid any sources of ignition.

    7.1.2  Advice on general occupational hygiene

    Good personal washing routines should be followed

    7.2    Condition for safe storage, including any incompatibilities

    Keep only in the original container in an appropriate place. 

    7.3    Specific end use(s)

    No specific precautions.

    8    EXPOSURE CONTROLS / PERSONAL PROTECTION

    8.1    Control parameters 

    Component

    CAS

    Concentration limit

    OEL (ppm)

    BENZYL ALCOHOL

    100-51-6

    >= 5 % - 10 %

    10 (AIHA)

    • Exposure controls

    8.2.1  Environmental exposure controls

     Discharge, treatment, or disposal may be subject to national, state, or local laws.

    8.2.2  Personal protective equipment (ppe)

    Respiratory protection: In case of inadequate ventilation use suitable respirator. Eye protection: Wear goggles/face shield.

    Hand protection: Gloves.

    Skin protection: Wear suitable protective clothing. Provide adequate ventilation if fumes or vapors are generated. 

    9    PHYSICAL AND CHEMICAL PROPERTIES

    9.1    Information on basic physical and chemical properties

    • Physical State: LIQUID
    • Color: From COLORLESS to YELLOW
    • Odor: Characteristic
    • pH: No data
    • Melting point (°C): No data
    • Boiling point (°C): No data
    • Flash point (°F): 82 °F (90.4°C)
    • Evaporation Rate: No data
    • Flammability (solid, gas): No data
    • Upper/lower limit on flammability or explosive limits: No data
    • Vapor pressure: No data
    • Vapor Density: No data
    • Specific Gravity: 9814 / 0.9914
    • Solubility: No data
    • Log Pow (n-Octanol/Water Partition Coefficient): No data
    • Auto Ignition (°C): No data available.
    • Decomposition temperature (°C): No data
    • Viscosity at 40°C: No data
    • Explosive properties: No data
    • Oxidizing properties: No data
    • Vapor pressure at 20°C: No data
    • Vapor pressure at 50°C: No data

    9.2    Other information

    No other information noted.

    10    STABILITY AND REACTIVITY

    10.1   Reactivity

    No data available.

    10.2   Chemical stability

    Stable under normal temperature conditions and recommended use.

    10.3   Possibility of hazardous reactions

    No data available.

    10.4   Conditions to avoid

    Store in a cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high temperatures

    10.5   Incompatible materials

    No data available.

    10.6   Hazardous decomposition products

    No data available. 

    11    TOXICOLOGICAL INFORMATION

    11.1   Information on toxicological effects

    Product Information

    LD50 Dermal(mg/kg)                                      > 5000 (Calculated)

    LD50 Oral(mg/kg)                                          3917.2 (Calculated)

    CL50 Inhalation - vapor(mg/l)                         > 100 (Calculated)

     

    11.2   Other toxicological data information

    This product has not been subject to toxicological testing as an entity. According to available data on the constituents, the health classification criteria are met.

    11.3   Information about carcinogens

    NTP: None IARC: None OSHA: None

    12    ECOLOGICAL INFORMATION

    12.1   Toxicity

    Product Information

    Toxicity Fish                                      :    No data available.

    Toxicity Alga                                      :    No data available.

    Toxicity Water Flea                            :    No data available.

    Toxicity Rat                                       :    No data available.

    12.2   Persistence and degradability

    Biodegradability                                                           :    No data available.

    Hydrosolubility                                                             :    No data available.

    Comments                                                                  :    None

    12.3   Other eco-toxicological information

    This product has not been subject to eco-toxicological testing as an entity. According to available data on the constituents, the environment classification criteria are met.

    Log Pow (n-Octanol/Water Partition Coefficient)                  : No data available. Bio Concentration Factor          : No data available.

    Bioaccumulative potential                                                   : No data available.

    Mobility in soil                                                                    : No data available.

    Other adverse effects                                                         : No data available.

     

    13    DISPOSAL CONSIDERATIONS

    13.1   Waste treatment methods

    Do not release into the environment. Confirm disposal procedures with environmental engineer and local regulations.

     

    13.2   Other information

    Always keep original label(s) on empty recipients (drums/pails).

     

    14    TRANSPORT INFORMATION

    DOT (Exceptions may apply)

    UN number                                                   3082

    Transportation name United Nations             : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

    ( PERFUMERY PRODUCTS )

    Danger class(es) for transport                      : Class 9 : MISCELLANEOUS DANGEROUS SUBSTANCES AND

    ARTICLES

    Packaging group                                           III

    Environmental dangers                                : Yes.

    IATA

    UN number                                                   3082

    Transportation name United Nations             : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

    ( PERFUMERY PRODUCTS )

    Danger class(es) for transport                      : Class 9 : MISCELLANEOUS DANGEROUS SUBSTANCES AND

    ARTICLES

    Packaging group                                           III

    Environmental dangers                                : Yes

    IMDG

    UN number                                                   3082

    Transportation name United Nations             : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

    ( PERFUMERY PRODUCTS )

    Danger class(es) for transport                       : Class 9 : MISCELLANEOUS DANGEROUS SUBSTANCES AND

    ARTICLES

    Packaging group                                           III

    Environmental dangers                                : Yes.

    Marine polutants                                          : P - pollutant


    15    REGULATORY INFORMATION

    Safety, health and environmental regulations/legislation specific for the substance or mixture: No recommendation given

    16    Other information

    16.1   Entire text of the H and P phrases mentioned in chapters 2 and 3:

    H226                                               Flammable liquid and vapor.

    H227                                               Combustible liquid.

    H228                                               Flammable solid.

    H302                                               Harmful if swallowed.

    H304                                               May be fatal if swallowed and enters airways.

    H315                                               Causes skin irritation.

    H317                                               May cause an allergic skin reaction.

    H319                                               Causes serious eye irritation.

    H320                                               Causes eye irritation.

    H332                                               Harmful if inhaled.

    H336                                               May cause drowsiness or dizziness.

    H400                                               Very toxic to aquatic life.

    H410                                               Very toxic to aquatic life with long lasting effects.

    H411                                               Toxic to aquatic life with long lasting effects.

    H412                                               Harmful to aquatic life with long lasting effects.

     

    P210                                               Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

    P280                                               Wear protective gloves/protective clothing/eye protection/face protection.

    P261                                               Avoid breathing dust/fume/gas/mist/vapors/spray.

    P273                                               Avoid release to the environment.

    P333+P313                                     If skin irritation or rash occurs: Get medical advice.

    P370+P378                                     In case of fire: Use water for extinction.

    P305+P351+P338                            IF IN EYES: Rinse with water for several minutes. Remove contact lenses, if

    present.

    P337+P313                                     If eye irritation persists: Get medical advice

    P302+P352                                     IF ON SKIN: Wash with plenty of soap and water. 

    P391                                               Collect spillage.

    P321                                               Specific treatment (see this label).

    P363                                               Wash contaminated clothing before reuse.

    P403+P235                                     Store in a well-ventilated place. Keep cool.

    P501                                               Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    P272                                               Contaminated work clothing should not be allowed out of the workplace.

    16.2   Abbreviation and acronyms

    CAS: Chemical Abstracts Service CO2: Carbon dioxyde

    LD50: Lethal dose 50

    NTP: National Toxicology program

    IARC: International Agency for Research on Cancer OSHA: Occupational Safety and Health Administration UN: United Nations

    IMDG : International Maritime Dangerous Goods IATA : International Air Transport Association

    16.3   Key literature references and sources for data

    This Safety Data Sheet has been prepared in accordance with the Hazard Communication Standard (HCS) and its amendements, promulgated by the US Occupational Safety and Health Administration (OSHA) – 29 CFR 1900.1200.

    We cannot be held responsible in the event of improper usage of this product. It is up to the user to analyse the information

    given and to determine appropriate handling conditions for the safe use of this product.

    It is the user's liability to conform to all local, national, and international regulations that apply to its activities. This automatically generated safety data sheet is valid without signature.